The mode is n-1, so the smallest two numbers must both be n-1, giving us:
n-1, n-1, n, _ , _
The mean is n+1, so the total of the five numbers is 5n+5, so the last two numbers must add up to 2n+7.
The fourth number must be greater than n (if it was n there would not be a unique mode) so it must be at least n+1. That would give a value of n+6 for the fifth number.
If the fourth number was any bigger, the fifth number would have to be smaller (giving us a smaller range), so this gives the maximum range:
n-1, n-1, n, n+1, n+6
The difference between n+6 and n-1 is 7,
so the maximum range is 7.