Answer: 4 more five-pence coins than two-pence coins
Forming an equation
Let the number of five-pence coins be x
So the number of two-pence coins is 50 - x
Then 5x + 2(50 - x) = 181, that is 3x = 81, that is x = 27.
So there are 27 five-pence coins and 23 two-pence coins, so there are 4 more five-pence coins than two-pence coins.
Starting from 25 of each coin
25\times2p + 25\times5p = 175p
Swap n\times2p for n\times5p to get 181p
175p -n\times2p + n\times5p = 181p \Rightarrow 175p + n(5p-2p) = 181p \Rightarrow 175p + n\times3p = 181p \Rightarrow n\times3p = 3p \Rightarrow n = 2
After swapping 2 2ps for 2 5ps there are 4 more 5ps than 2ps